58 Ce 140.1161

Cerium

lanthanide · period 6 · group 3 · f-block

Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air, and it is soft enough to be cut with a steel kitchen knife.

What the numbers say

At standard temperature and pressure Cerium is a solid, sitting in period 6, group 3 of the f-block.

Its melting point of 1068 K (795 °C) is the 63rd highest of the 110 elements with a measured value — mid-range among the elements.

At 6.689 g/cm³ it is the 52nd densest of 96 elements with a quoted density.

Pauling electronegativity is 1.12. Paired with oxygen (3.44) that is a difference of 2.32, which puts the bond predominantly ionic — expect a stable oxide ceramic.

In the solid state it takes a simple hexagonal structure — hexagonal packing offers few easy slip systems, so properties are anisotropic and formability is limited.

It is reported in 3 oxidation states (2, 3, 4), which sets how many distinct compounds and phases it can form.

First identified in 1803.

Crystal structure

a b c Simple Hexagonal

Solid Cerium adopts a Simple Hexagonal arrangement, in the Hexagonal system — axes a = b ≠ c, angles α = β = 90°, γ = 120°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Ce — with DFT formation energy, hull stability and band gap where the provider publishes them.

Ce

K 2 · L 8 · M 18 · N 19 · O 9 · P 2

Properties

Atomic number 58
Atomic mass 140.1161 u
Series lanthanide
Group 3
Period 6
Block f-block
Phase at STP Solid
Density 6.689 g/cm³
Melting point 1068 K (795 °C)
Boiling point 3716 K (3443 °C)
Electronegativity (Pauling) 1.12
Electron configuration [Xe] 4f¹ 5d¹ 6s²
Crystal structure Simple Hexagonal
Oxidation states 2,3,4
Discovered 1803

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See Ce in context with all 118 elements.

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