69 Tm 168.934222

Thulium

lanthanide · period 6 · group 3 · f-block

Thulium is a chemical element with the symbol Tm and atomic number 69. It is the thirteenth and third-last element in the lanthanide series.

What the numbers say

At standard temperature and pressure Thulium is a solid, sitting in period 6, group 3 of the f-block.

Its melting point of 1818 K (1545 °C) is the 25th highest of the 110 elements with a measured value — mid-range among the elements.

At 9.32 g/cm³ it is the 30th densest of 96 elements with a quoted density.

Pauling electronegativity is 1.25. Paired with oxygen (3.44) that is a difference of 2.19, which puts the bond predominantly ionic — expect a stable oxide ceramic.

In the solid state it takes a simple hexagonal structure — hexagonal packing offers few easy slip systems, so properties are anisotropic and formability is limited.

It is reported in 2 oxidation states (2, 3), which sets how many distinct compounds and phases it can form.

First identified in 1879.

Crystal structure

a b c Simple Hexagonal

Solid Thulium adopts a Simple Hexagonal arrangement, in the Hexagonal system — axes a = b ≠ c, angles α = β = 90°, γ = 120°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Tm — with DFT formation energy, hull stability and band gap where the provider publishes them.

Tm

K 2 · L 8 · M 18 · N 31 · O 8 · P 2

Properties

Atomic number 69
Atomic mass 168.934222 u
Series lanthanide
Group 3
Period 6
Block f-block
Phase at STP Solid
Density 9.32 g/cm³
Melting point 1818 K (1545 °C)
Boiling point 2223 K (1950 °C)
Electronegativity (Pauling) 1.25
Electron configuration [Xe] 4f¹³ 6s²
Crystal structure Simple Hexagonal
Oxidation states 2,3
Discovered 1879

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See Tm in context with all 118 elements.

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