12 Mg 24.305

Magnesium

alkaline earth metal · period 3 · group 2 (alkaline earth metals) · s-block

Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray solid which bears a close physical resemblance to the other five elements in the second column (group 2, or alkaline earth metals) of the periodic table: all group 2 elements have the same electron configuration in the outer electron shell and a similar crystal structure. This element is produced in large, aging stars from the sequential addition of three helium nuclei to a carbon nucleus.

What the numbers say

At standard temperature and pressure Magnesium is a solid, sitting in period 3, group 2 of the s-block.

Its melting point of 923 K (650 °C) is the 67th highest of the 110 elements with a measured value — mid-range among the elements.

At 1.738 g/cm³ it is the 80th densest of 96 elements with a quoted density.

Pauling electronegativity is 1.31. Paired with oxygen (3.44) that is a difference of 2.13, which puts the bond predominantly ionic — expect a stable oxide ceramic.

In the solid state it takes a simple hexagonal structure — hexagonal packing offers few easy slip systems, so properties are anisotropic and formability is limited.

It is reported in 2 oxidation states (1, 2), which sets how many distinct compounds and phases it can form.

First identified in 1755.

Crystal structure

a b c Simple Hexagonal

Solid Magnesium adopts a Simple Hexagonal arrangement, in the Hexagonal system — axes a = b ≠ c, angles α = β = 90°, γ = 120°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Where magnesium shows up in engineering materials

1 entry in the materials library names it directly:

Crystallographic examples

Magnesium or one of its compounds is a textbook example for these crystal systems:

  • Cubic (isometric)Cu, Al, Fe-α (BCC), NaCl, diamond, spinel MgAl₂O₄
  • HexagonalMg, Zn, Ti-α, graphite, ZnO (wurtzite), ice Ih

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Mg — with DFT formation energy, hull stability and band gap where the provider publishes them.

Mg

K 2 · L 8 · M 2

Properties

Atomic number 12
Atomic mass 24.305 u
Series alkaline earth metal
Group 2
Period 3
Block s-block
Phase at STP Solid
Density 1.738 g/cm³
Melting point 923 K (650 °C)
Boiling point 1363 K (1090 °C)
Electronegativity (Pauling) 1.31
Electron configuration [Ne] 3s²
Crystal structure Simple Hexagonal
Oxidation states 1,2
Discovered 1755

Group 2 — alkaline earth metals

Other alkaline earth metals

← Back to the periodic table

See Mg in context with all 118 elements.

Working with magnesium in a real design?

Ask the materials chat how Mg behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.