15 P 30.9737619985

Phosphorus

polyatomic nonmetal · period 3 · group 15 (pnictogens) · p-block

Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Earth.

What the numbers say

At standard temperature and pressure Phosphorus is a solid, sitting in period 3, group 15 of the p-block.

Its melting point of 317 K (44 °C) is the 92nd highest of the 110 elements with a measured value — mid-range among the elements.

At 1.823 g/cm³ it is the 79th densest of 96 elements with a quoted density.

Pauling electronegativity is 2.19. Paired with oxygen (3.44) that is a difference of 1.25, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a simple triclinic structure.

It is reported in 8 oxidation states (-3, -2, -1, 1, 2, 3, 4, 5), which sets how many distinct compounds and phases it can form.

First identified in 1669.

Crystal structure

a b c Simple Triclinic

Solid Phosphorus adopts a Simple Triclinic arrangement, in the Triclinic system — axes a ≠ b ≠ c, angles α ≠ β ≠ γ ≠ 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing P — with DFT formation energy, hull stability and band gap where the provider publishes them.

P

K 2 · L 8 · M 5

Properties

Atomic number 15
Atomic mass 30.9737619985 u
Series polyatomic nonmetal
Group 15
Period 3
Block p-block
Phase at STP Solid
Density 1.823 g/cm³
Melting point 317.3 K (44 °C)
Boiling point 553.6 K (280 °C)
Electronegativity (Pauling) 2.19
Electron configuration [Ne] 3s² 3p³
Crystal structure Simple Triclinic
Oxidation states -3,-2,-1,1,2,3,4,5
Discovered 1669

Group 15 — pnictogens

Other polyatomic nonmetals

← Back to the periodic table

See P in context with all 118 elements.

Working with phosphorus in a real design?

Ask the materials chat how P behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.