6 C 12.011

Carbon

polyatomic nonmetal · period 2 · group 14 · p-block

Carbon (from Latin: carbo "coal") is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds.

What the numbers say

At standard temperature and pressure Carbon is a solid, sitting in period 2, group 14 of the p-block.

Its melting point of 3823 K (3550 °C) is the 1st highest of the 110 elements with a measured value — one of the most refractory elements there is.

At 2.26 g/cm³ it is the 75th densest of 96 elements with a quoted density.

Pauling electronegativity is 2.55. Paired with oxygen (3.44) that is a difference of 0.89, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a simple hexagonal structure — hexagonal packing offers few easy slip systems, so properties are anisotropic and formability is limited.

It is reported in 8 oxidation states (-4, -3, -2, -1, 1, 2, 3, 4), which sets how many distinct compounds and phases it can form.

First identified in c. 3750 BCE.

Crystal structure

a b c Simple Hexagonal

Solid Carbon adopts a Simple Hexagonal arrangement, in the Hexagonal system — axes a = b ≠ c, angles α = β = 90°, γ = 120°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Where carbon shows up in engineering materials

3 entries in the materials library name it directly:

Crystallographic examples

Carbon or one of its compounds is a textbook example for this crystal system:

  • Orthorhombicα-S, cementite Fe₃C, aragonite CaCO₃, olivine

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing C — with DFT formation energy, hull stability and band gap where the provider publishes them.

C

K 2 · L 4

Properties

Atomic number 6
Atomic mass 12.011 u
Series polyatomic nonmetal
Group 14
Period 2
Block p-block
Phase at STP Solid
Density 2.26 g/cm³
Melting point 3823 K (3550 °C)
Boiling point 4300 K (4027 °C)
Electronegativity (Pauling) 2.55
Electron configuration [He] 2s² 2p²
Crystal structure Simple Hexagonal
Oxidation states -4,-3,-2,-1,1,2,3,4
Discovered c. 3750 BCE

Other polyatomic nonmetals

← Back to the periodic table

See C in context with all 118 elements.

Working with carbon in a real design?

Ask the materials chat how C behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.