8 O 15.999

Oxygen

diatomic nonmetal · period 2 · group 16 (chalcogens) · p-block

Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds.

What the numbers say

At standard temperature and pressure Oxygen is a gas, sitting in period 2, group 16 of the p-block.

Its melting point of 54 K (-219 °C) is the 106th highest of the 110 elements with a measured value — among the lowest-melting elements.

At 0.001 g/cm³ it is the 92nd densest of 96 elements with a quoted density.

In the solid state it takes a base-centered monoclinic structure.

It is reported in 4 oxidation states (-2, -1, 1, 2), which sets how many distinct compounds and phases it can form.

First identified in 1774.

Crystal structure

a b c Base-centered Monoclinic

Solid Oxygen adopts a Base-centered Monoclinic arrangement, in the Monoclinic system — axes a ≠ b ≠ c, angles α = γ = 90°, β ≠ 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Where oxygen shows up in engineering materials

1 entry in the materials library names it directly:

Crystallographic examples

Oxygen or one of its compounds is a textbook example for these crystal systems:

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing O — with DFT formation energy, hull stability and band gap where the provider publishes them.

O

K 2 · L 6

Properties

Atomic number 8
Atomic mass 15.999 u
Series diatomic nonmetal
Group 16
Period 2
Block p-block
Phase at STP Gas
Density 0.001 g/cm³
Melting point 54.36 K (-219 °C)
Boiling point 90.19 K (-183 °C)
Electronegativity (Pauling) 3.44
Electron configuration [He] 2s² 2p⁴
Crystal structure Base-centered Monoclinic
Oxidation states -2,-1,1,2
Discovered 1774

Group 16 — chalcogens

Other diatomic nonmetals

← Back to the periodic table

See O in context with all 118 elements.

Working with oxygen in a real design?

Ask the materials chat how O behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.