Iodine
diatomic nonmetal · period 5 · group 17 (halogens) · p-block
Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at 114 degrees Celsius, and boils to a violet gas at 184 degrees Celsius.
What the numbers say
At standard temperature and pressure Iodine is a solid, sitting in period 5, group 17 of the p-block.
Its melting point of 387 K (114 °C) is the 88th highest of the 110 elements with a measured value — mid-range among the elements.
At 4.94 g/cm³ it is the 64th densest of 96 elements with a quoted density.
Pauling electronegativity is 2.66. Paired with oxygen (3.44) that is a difference of 0.78, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.
In the solid state it takes a base orthorhombic structure.
It is reported in 6 oxidation states (-1, 1, 3, 4, 5, 7), which sets how many distinct compounds and phases it can form.
First identified in 1811.
Crystal structure
Solid Iodine adopts a Base Orthorhombic arrangement, in the Orthorhombic system — axes a ≠ b ≠ c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.
Check it against computed structures
The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing I — with DFT formation energy, hull stability and band gap where the provider publishes them.
K 2 · L 8 · M 18 · N 18 · O 7
Properties
| Atomic number | 53 |
|---|---|
| Atomic mass | 126.904473 u |
| Series | diatomic nonmetal |
| Group | 17 |
| Period | 5 |
| Block | p-block |
| Phase at STP | Solid |
| Density | 4.94 g/cm³ |
| Melting point | 386.85 K (114 °C) |
| Boiling point | 457.4 K (184 °C) |
| Electronegativity (Pauling) | 2.66 |
| Electron configuration | [Kr] 4d¹⁰ 5s² 5p⁵ |
| Crystal structure | Base Orthorhombic |
| Oxidation states | -1,1,3,4,5,7 |
| Discovered | 1811 |
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See I in context with all 118 elements.
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