46 Pd 106.421

Palladium

transition metal · period 5 · group 10 · d-block

Palladium is a chemical element with the symbol Pd and atomic number 46. It is a rare and lustrous silvery-white metal discovered in 1803 by the English chemist William Hyde Wollaston.

What the numbers say

At standard temperature and pressure Palladium is a solid, sitting in period 5, group 10 of the d-block.

Its melting point of 1828 K (1555 °C) is the 24th highest of the 110 elements with a measured value — mid-range among the elements.

At 12.023 g/cm³ it is the 20th densest of 96 elements with a quoted density.

Pauling electronegativity is 2.2. Paired with oxygen (3.44) that is a difference of 1.24, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a face-centered cubic structure — FCC packing gives 12 independent slip systems, which is why FCC metals are the ductile, formable ones.

It is reported in 2 oxidation states (2, 4), which sets how many distinct compounds and phases it can form.

First identified in 1803.

Crystal structure

a b c Face-centered Cubic

Solid Palladium adopts a Face-centered Cubic arrangement, in the Cubic (isometric) system — axes a = b = c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Pd — with DFT formation energy, hull stability and band gap where the provider publishes them.

Pd

K 2 · L 8 · M 18 · N 18

Properties

Atomic number 46
Atomic mass 106.421 u
Series transition metal
Group 10
Period 5
Block d-block
Phase at STP Solid
Density 12.023 g/cm³
Melting point 1828.05 K (1555 °C)
Boiling point 3236 K (2963 °C)
Electronegativity (Pauling) 2.2
Electron configuration [Kr] 4d¹⁰
Crystal structure Face-centered Cubic
Oxidation states 2,4
Discovered 1803

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See Pd in context with all 118 elements.

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