23 V 50.94151

Vanadium

transition metal · period 4 · group 5 · d-block

Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal.

What the numbers say

At standard temperature and pressure Vanadium is a solid, sitting in period 4, group 5 of the d-block.

Its melting point of 2183 K (1910 °C) is the 15th highest of the 110 elements with a measured value — mid-range among the elements.

At 6.11 g/cm³ it is the 58th densest of 96 elements with a quoted density.

Pauling electronegativity is 1.63. Paired with oxygen (3.44) that is a difference of 1.81, which puts the bond predominantly ionic — expect a stable oxide ceramic.

In the solid state it takes a body-centered cubic structure — BCC packing is stronger but shows a ductile-to-brittle transition as temperature drops.

It is reported in 6 oxidation states (-1, 1, 2, 3, 4, 5), which sets how many distinct compounds and phases it can form.

First identified in 1801.

Crystal structure

a b c Body-centered Cubic

Solid Vanadium adopts a Body-centered Cubic arrangement, in the Cubic (isometric) system — axes a = b = c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing V — with DFT formation energy, hull stability and band gap where the provider publishes them.

V

K 2 · L 8 · M 11 · N 2

Properties

Atomic number 23
Atomic mass 50.94151 u
Series transition metal
Group 5
Period 4
Block d-block
Phase at STP Solid
Density 6.11 g/cm³
Melting point 2183 K (1910 °C)
Boiling point 3680 K (3407 °C)
Electronegativity (Pauling) 1.63
Electron configuration [Ar] 3d³ 4s²
Crystal structure Body-centered Cubic
Oxidation states -1,1,2,3,4,5
Discovered 1801

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See V in context with all 118 elements.

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