48 Cd 112.4144

Cadmium

transition metal · period 5 · group 12 · d-block

Cadmium is a chemical element with the symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury.

What the numbers say

At standard temperature and pressure Cadmium is a solid, sitting in period 5, group 12 of the d-block.

Its melting point of 594 K (321 °C) is the 78th highest of the 110 elements with a measured value — mid-range among the elements.

At 8.65 g/cm³ it is the 37th densest of 96 elements with a quoted density.

Pauling electronegativity is 1.69. Paired with oxygen (3.44) that is a difference of 1.75, which puts the bond predominantly ionic — expect a stable oxide ceramic.

In the solid state it takes a simple hexagonal structure — hexagonal packing offers few easy slip systems, so properties are anisotropic and formability is limited.

It is reported in 2 oxidation states (1, 2), which sets how many distinct compounds and phases it can form.

First identified in 1817.

Crystal structure

a b c Simple Hexagonal

Solid Cadmium adopts a Simple Hexagonal arrangement, in the Hexagonal system — axes a = b ≠ c, angles α = β = 90°, γ = 120°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Cd — with DFT formation energy, hull stability and band gap where the provider publishes them.

Cd

K 2 · L 8 · M 18 · N 18 · O 2

Properties

Atomic number 48
Atomic mass 112.4144 u
Series transition metal
Group 12
Period 5
Block d-block
Phase at STP Solid
Density 8.65 g/cm³
Melting point 594.22 K (321 °C)
Boiling point 1040 K (767 °C)
Electronegativity (Pauling) 1.69
Electron configuration [Kr] 4d¹⁰ 5s²
Crystal structure Simple Hexagonal
Oxidation states 1,2
Discovered 1817

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See Cd in context with all 118 elements.

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