45 Rh 102.905502

Rhodium

transition metal · period 5 · group 9 · d-block

Rhodium is a chemical element with the symbol Rh and atomic number 45. It is an extraordinarily rare, silvery-white, hard, corrosion-resistant, and chemically inert transition metal.

What the numbers say

At standard temperature and pressure Rhodium is a solid, sitting in period 5, group 9 of the d-block.

Its melting point of 2237 K (1964 °C) is the 14th highest of the 110 elements with a measured value — mid-range among the elements.

At 12.45 g/cm³ it is the 18th densest of 96 elements with a quoted density.

Pauling electronegativity is 2.28. Paired with oxygen (3.44) that is a difference of 1.16, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a face-centered cubic structure — FCC packing gives 12 independent slip systems, which is why FCC metals are the ductile, formable ones.

It is reported in 7 oxidation states (-1, 1, 2, 3, 4, 5, 6), which sets how many distinct compounds and phases it can form.

First identified in 1803.

Crystal structure

a b c Face-centered Cubic

Solid Rhodium adopts a Face-centered Cubic arrangement, in the Cubic (isometric) system — axes a = b = c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Rh — with DFT formation energy, hull stability and band gap where the provider publishes them.

Rh

K 2 · L 8 · M 18 · N 16 · O 1

Properties

Atomic number 45
Atomic mass 102.905502 u
Series transition metal
Group 9
Period 5
Block d-block
Phase at STP Solid
Density 12.45 g/cm³
Melting point 2237 K (1964 °C)
Boiling point 3968 K (3695 °C)
Electronegativity (Pauling) 2.28
Electron configuration [Kr] 4d⁸ 5s¹
Crystal structure Face-centered Cubic
Oxidation states -1,1,2,3,4,5,6
Discovered 1803

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See Rh in context with all 118 elements.

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