77 Ir 192.2173

Iridium

transition metal · period 6 · group 9 · d-block

Iridium is a chemical element with the symbol Ir and atomic number 77. A very hard, brittle, silvery-white transition metal of the platinum group, iridium is considered to be the second-densest naturally occurring metal (after osmium) with a density of 22.56 g/cm3 as defined by experimental X-ray crystallography.

What the numbers say

At standard temperature and pressure Iridium is a solid, sitting in period 6, group 9 of the d-block.

Its melting point of 2719 K (2446 °C) is the 8th highest of the 110 elements with a measured value — one of the most refractory elements there is.

At 22.56 g/cm³ it is the 2nd densest of 96 elements with a quoted density.

Pauling electronegativity is 2.2. Paired with oxygen (3.44) that is a difference of 1.24, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a face-centered cubic structure — FCC packing gives 12 independent slip systems, which is why FCC metals are the ductile, formable ones.

It is reported in 10 oxidation states (-3, -1, 1, 2, 3, 4, 5, 6, 7, 8), which sets how many distinct compounds and phases it can form.

First identified in 1803.

Crystal structure

a b c Face-centered Cubic

Solid Iridium adopts a Face-centered Cubic arrangement, in the Cubic (isometric) system — axes a = b = c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Ir — with DFT formation energy, hull stability and band gap where the provider publishes them.

Ir

K 2 · L 8 · M 18 · N 32 · O 15 · P 2

Properties

Atomic number 77
Atomic mass 192.2173 u
Series transition metal
Group 9
Period 6
Block d-block
Phase at STP Solid
Density 22.56 g/cm³
Melting point 2719 K (2446 °C)
Boiling point 4403 K (4130 °C)
Electronegativity (Pauling) 2.2
Electron configuration [Xe] 4f¹⁴ 5d⁷ 6s²
Crystal structure Face-centered Cubic
Oxidation states -3,-1,1,2,3,4,5,6,7,8
Discovered 1803

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See Ir in context with all 118 elements.

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