Bromine
diatomic nonmetal · period 4 · group 17 (halogens) · p-block
Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour.
What the numbers say
At standard temperature and pressure Bromine is a liquid, sitting in period 4, group 17 of the p-block.
Its melting point of 266 K (-7 °C) is the 97th highest of the 110 elements with a measured value — mid-range among the elements.
At 3.12 g/cm³ it is the 69th densest of 96 elements with a quoted density.
Pauling electronegativity is 2.96. Paired with oxygen (3.44) that is a difference of 0.48, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.
In the solid state it takes a base orthorhombic structure.
It is reported in 6 oxidation states (-1, 1, 3, 4, 5, 7), which sets how many distinct compounds and phases it can form.
First identified in 1826.
Crystal structure
Solid Bromine adopts a Base Orthorhombic arrangement, in the Orthorhombic system — axes a ≠ b ≠ c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.
Check it against computed structures
The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Br — with DFT formation energy, hull stability and band gap where the provider publishes them.
K 2 · L 8 · M 18 · N 7
Properties
| Atomic number | 35 |
|---|---|
| Atomic mass | 79.904 u |
| Series | diatomic nonmetal |
| Group | 17 |
| Period | 4 |
| Block | p-block |
| Phase at STP | Liquid |
| Density | 3.12 g/cm³ |
| Melting point | 265.8 K (-7 °C) |
| Boiling point | 332 K (59 °C) |
| Electronegativity (Pauling) | 2.96 |
| Electron configuration | [Ar] 3d¹⁰ 4s² 4p⁵ |
| Crystal structure | Base Orthorhombic |
| Oxidation states | -1,1,3,4,5,7 |
| Discovered | 1826 |
← Back to the periodic table
See Br in context with all 118 elements.
Working with bromine in a real design?
Ask the materials chat how Br behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.