35 Br 79.904

Bromine

diatomic nonmetal · period 4 · group 17 (halogens) · p-block

Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour.

What the numbers say

At standard temperature and pressure Bromine is a liquid, sitting in period 4, group 17 of the p-block.

Its melting point of 266 K (-7 °C) is the 97th highest of the 110 elements with a measured value — mid-range among the elements.

At 3.12 g/cm³ it is the 69th densest of 96 elements with a quoted density.

Pauling electronegativity is 2.96. Paired with oxygen (3.44) that is a difference of 0.48, which puts the bond polar covalent — oxides here tend to be semiconducting or refractory rather than salt-like.

In the solid state it takes a base orthorhombic structure.

It is reported in 6 oxidation states (-1, 1, 3, 4, 5, 7), which sets how many distinct compounds and phases it can form.

First identified in 1826.

Crystal structure

a b c Base Orthorhombic

Solid Bromine adopts a Base Orthorhombic arrangement, in the Orthorhombic system — axes a ≠ b ≠ c, angles α = β = γ = 90°. Symmetry controls the anisotropy of stiffness and thermal expansion, and the available slip systems set how far the metal deforms before it fractures.

Check it against computed structures

The structure search queries the Materials Project, OQMD and the Open Materials Database for computed crystal structures containing Br — with DFT formation energy, hull stability and band gap where the provider publishes them.

Br

K 2 · L 8 · M 18 · N 7

Properties

Atomic number 35
Atomic mass 79.904 u
Series diatomic nonmetal
Group 17
Period 4
Block p-block
Phase at STP Liquid
Density 3.12 g/cm³
Melting point 265.8 K (-7 °C)
Boiling point 332 K (59 °C)
Electronegativity (Pauling) 2.96
Electron configuration [Ar] 3d¹⁰ 4s² 4p⁵
Crystal structure Base Orthorhombic
Oxidation states -1,1,3,4,5,7
Discovered 1826

Group 17 — halogens

Other diatomic nonmetals

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See Br in context with all 118 elements.

Working with bromine in a real design?

Ask the materials chat how Br behaves in your alloy system, what it does to weldability, and which grades to look at — with the source of every number named.